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Tetra-kis(pyridazine-?N)bis-(seleno-cyanato-?N)cobalt(II) pyridazine disolvate.

ABSTRACT: Reaction of cobalt(II) nitrate with potassium seleno-cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio-cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno-cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.

SUBMITTER: Wohlert S 

PROVIDER: S-EPMC3393216 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Tetra-kis(pyridazine-κN)bis-(seleno-cyanato-κN)cobalt(II) pyridazine disolvate.

Wöhlert Susanne S   Wriedt Mario M   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20120623 Pt 7

Reaction of cobalt(II) nitrate with potassium seleno-cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio-cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno-cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazi  ...[more]

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