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Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II).

ABSTRACT: In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate methylphenyl-diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O-Pd-N bond angles of 89.60?(11) and 90.40?(11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966?(3) and 2.009?(3)?Å, respectively.

SUBMITTER: Lin ML

PROVIDER: S-EPMC3007315 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II).

Lin Meng-Ling ML Tsai Chen-Yen CY Li Chen-Yu CY Huang Bor-Hunn BH Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate methylphenyl-diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O-Pd-N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966 (3) and 2 ...[more]

PMID: 21588097

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