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Bis{1-[(E)-o-tolyl-diazen-yl]-2-naphtho-l-ato}copper(II).

ABSTRACT: In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl-diazen-yl]-2-naphtho-late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, with an O-Cu-O bond angle of 177.00?(9)° and an N-Cu-N bond angle of 165.63?(10)°. The average distances between the Cu(II) atom and the coordinated O and N atoms are 1.905?(2) and 1.995?(2)Å, respectively.

SUBMITTER: Tai WJ

PROVIDER: S-EPMC2983183 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Bis{1-[(E)-o-tolyl-diazen-yl]-2-naphtho-l-ato}copper(II).

Tai Wan-Ju WJ Li Chi-Huan CH Li Chen-Yu CY Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl-diazen-yl]-2-naphtho-late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, with an O-Cu-O bond angle of 177.00 (9)° and an N-Cu-N bond angle of 165.63 (10)°. The average distances between the Cu(II) atom and the coordinated O and N atoms are 1.905 (2) an ...[more]

PMID: 21587451

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