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Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-κN,O}copper(II).

ABSTRACT: In the title complex, [Cu(C(18)H(14)NO)(2)], the Cu(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms.

SUBMITTER: Zhu P

PROVIDER: S-EPMC3008097 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-?N,O}nickel(II).

Project description:In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methyl-phenyl group is 49.03?(7)°.

| S-EPMC3099807 | biostudies-other

Bis{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(I) tetra-phenyl-borate.

Project description:In the crystal structure of the title compound, [Cu(C(12)H(9)BrN(2))(2)](C(24)H(20)B), the copper(I) cation is coordinated by four N atoms of two crystallographically independent 2-[(4-bromo-phen-yl)imino-meth-yl]pyridine ligands within a distorted tetra-hedron.

| S-EPMC2961942 | biostudies-literature

Bis{2-[(E)-benzyl-imino-meth-yl]-4-methyl-phen-olato-κN,O}cobalt(II).

Project description:In the title complex, [Co(C(15)H(14)NO)(2)], the Co(II) atom, situated on an inversion centre, is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a slightly distorted square-planar geometry. The two phenolate rings form a dihedral angle of 10.53 (2)°.

| S-EPMC2960051 | biostudies-literature

Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).

Project description:The title compound, [Cu2(C9H10NO2)4], is built of discrete centrosymmetric dimers. The Cu(II) atoms are each five coordinated by two deprotonated Schiff base ligands that are bonded differently to the metal atoms. Of the two phenolate O atoms, one is coordinated to one Cu(II) atom, whereas another bridges the two metal atoms. The basal plane of the square pyramid around Cu(II) atoms is formed by the imino N and phenolate O atoms of the bidentate and the monodentate/bidentate Schiff base ligands. The bridging phenolate oxygen occupies the apical position of the coordination sphere with a considerably longer Cu-O bond length. In the crystal, the dimeric mol-ecules pack relative to each other in such a way that the Cu2O2 planes of adjacent dimers are orthogonal.

| S-EPMC3790358 | biostudies-literature

Bis{2-[(2,4-dimethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}bis-(thio-cyanato-κN)cadmium.

Project description:The title compound, [Cd(NCS)(2)(C(14)H(14)N(2))(2)], features crystallographic inversion symmetry with the Cd(II) ion located on a centre of inversion. The Cd(II) ion is six-coordinated in a slightly distorted octa-hedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An inter-molecular C-H⋯S hydrogen bond stabilizes the crystal structure.

| S-EPMC3274934 | biostudies-literature

Di-μ-chlorido-bis-(chlorido{2-[(4-ethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(II)).

Project description:The binuclear title complex, [Cu(2)Cl(4)(C(14)H(14)N(2))(2)], is located on a crystallographic inversion centre. The Cu(II) ion is in a distorted square-pyramid coordination environment formed by the bichelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Cu-Cl bonds is significantly longer than the other.

| S-EPMC3200970 | biostudies-literature

Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II).

Project description:In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate methylphenyl-diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O-Pd-N bond angles of 89.60?(11) and 90.40?(11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966?(3) and 2.009?(3)?Å, respectively.

| S-EPMC3007315 | biostudies-literature

Dichlorido{2-[(4-iodo-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(II).

Project description:The Cu(II) atom in the title complex, [CuCl(2)(C(12)H(9)IN(2))], has a square-planar coordination being N,N'-chelated by the Schiff base ligand, and by two Cl atoms. The geometry is distorted towards square pyramidal owing to a long Cu⋯Cl inter-action of 2.941 (1) Å. This results in the formation of a zigzag chain structure propagating in the c-axis direction.

| S-EPMC2977602 | biostudies-literature

Bis{2-[(2-cyano-phen-yl)imino-meth-yl]phenolato}copper(II).

Project description:In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu-N and Cu-O bond lengths are 2.009 (2) and 1.888 (2) Å, respectively. The dihedral angle between the cyano-phenyl rings and phenolate rings is 42.28 (13)°.

| S-EPMC2959947 | biostudies-literature

Bis{(E)-2-[1-(eth-oxy-imino)-eth-yl]-1-naphtho-lato-?N,O}copper(II).

Project description:In the title complex, [Cu(C(14)H(14)NO(2))(2)], the discrete complex mol-ecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the Cu(II) atom comprises two phenolate O atoms and two oxime N atoms from two bidentate-chelate 2-[1-(eth-oxy-imino)-eth-yl]-1-naphtho-late O-ethyl oxime (L(-)) ligands [Cu-O = 1.8919?(17)?Å and Cu-N = 1.988?(2)?Å]. The two naphthalene ring systems in the mol-ecule are parallel, with a perpendicular inter-planar spacing of 1.473?(2)?Å, while each complex unit forms links to four other mol-ecules via inter-molecular methyl C-H?? inter-actions, giving an infinite cross-linked layered supra-molecular structure.

| S-EPMC3011585 | biostudies-literature

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