Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[triphenyl-tin(IV)]-?-2-(cyclo-hexyl-amino-carbon-yl)benzoato-?O:O].

ABSTRACT: In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl-tin cations are bridged by the N-cyclo-hexyl-phthalamate anion through the carboxyl-ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl-ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal.

SUBMITTER: Imtiaz-Ud-Din

PROVIDER: S-EPMC3007350 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[[triphenyl-tin(IV)]-μ-2-(cyclo-hexyl-amino-carbon-yl)benzoato-κO:O].

Imtiaz-Ud-Din Raqiqt-Ul-Rasool Bhatti Moazzam H MH Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl-tin cations are bridged by the N-cyclo-hexyl-phthalamate anion through the carboxyl-ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl-ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal. ...[more]

PMID: 21588163

Similar Datasets

catena-Poly[[triphenyl-tin(IV)]-?(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-?O:O]].

Project description:The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H?O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand.

| S-EPMC2983217 | biostudies-literature

catena-Poly[[triphenyl-tin(IV)]-?-5-amino-2-nitro-benzoato-?O:O].

Project description:The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal-bipyramidal geometry by two monodentate carboxyl-ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl-ate groups [O-Sn-O = 170.88?(3)°]. The benzene ring of the 5-amino-2-nitro-benzoate ligand forms dihedral angles of 82.92?(6), 81.10?(6) and 83.54?(6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter-molecular N-H?O and weak C-H?O inter-actions into a three-dimensional network. The crystal structure is further stabilized by weak inter-molecular C-H?? inter-actions.

| S-EPMC3200871 | biostudies-other

[3-(Dimethyl-amino)benzoato]triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl-ate anion in a distorted tetra-hedral geometry. An intra-molecular C-H?O inter-action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other three phenyl rings are 76.94?(8), 66.82?(8) and 42.34?(9)°. The crystal structure is further stabilized by inter-molecular C-H?? inter-actions.

| S-EPMC2959792 | biostudies-literature

catena-Poly[[cyclo-hexyl-diphenyl-tin(IV)]-?-hydroxido-?O:O].

Project description:The title polymeric mixed-organyl tin hydroxide, [Sn(C(6)H(5))(2)(C(6)H(11))(OH)](n), hass a hydroxide-bridged chain structure; the tin center shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The Sn atom lies on a special position of site symmetry m; the symmetry element relates one phenyl ring to the other and also relates one half of the cyclo-hexyl ring to the other half.

| S-EPMC2961296 | biostudies-other

(2-Amino-3-nitro-benzoato-?O)triphenyl-tin(IV).

Project description:The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent mol-ecules. In each mol-ecule, the four-coordinated Sn(IV) atom exists in a distorted tetra-hedral geometry and two intra-molecular N-H?O hydrogen bonds with S(6) ring motifs are present. In one mol-ecule, the benzene ring of the 2-amino-3-nitro-benzoate ligand makes dihedral angles of 42.74?(11), 89.66?(13) and 53.04?(10)° with the three phenyl rings. The corresponding dihedral angles for the other mol-ecule are 6.29?(11), 66.55?(11) and 62.33?(10)°. In the crystal, a weak inter-molecular C-H?? inter-action and a ?-? stacking inter-action with a centroid-centroid distance of 3.5877?(12)?Å are observed.

| S-EPMC3089114 | biostudies-literature

catena-Poly[[triphenyl-tin(IV)]-?-phenyl-phosphinato-?O:O'].

Project description:In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H?? inter-actions, forming a two-dimensional network lying parallel to (001).

| S-EPMC3238605 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-3,5-difluoro-benzoato-?O:O'].

Project description:In the title compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxyl-ate ligands. The five-coordinate Sn atom exists in a distorted trigonal-bipyramidal geometry with the mol-ecules connected by weak C-H?F inter-moleclar inter-actions, forming supra-molecular chains parallel to [010].

| S-EPMC3212122 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2,4,6-trichloro-benzoato].

Project description:In the title compound, [Sn(CH(3))(3)(C(7)H(2)Cl(3)O(2))](n), the tin(IV) atom exhibits a slightly distorted trigonal-bipyramidal geometry with two O atoms of symmetry-related carboxyl-ate groups in the axial positions and three methyl groups in the equatorial positions. In the crystal structure, the metal atoms are linked by carboxyl-ate bridges into polymeric chains extending along the b axis.

| S-EPMC2967877 | biostudies-other

catena-Poly[[dimethyl-tin(IV)]-?-cis-cyclo-hexane-1,2-dicarboxyl-ato].

Project description:The title complex, [Sn(CH(3))(2)(C(8)H(10)O(4))](n), was synthesized from cis-cyclo-hexane-1,2-dicarboxylic acid and dimethyl-tin dichloride. The complex has a bridging bis-bidentate carboxyl-ate group resulting in a zig-zag chain structure parallel to [001]. The Sn atom is six-coordinated and displays a distorted octa-hedral geometry.

| S-EPMC2968691 | biostudies-literature

(4-Chloro-3-nitro-benzoato)triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))], the four-coordinate Sn(IV) atom exists in a distorted tetra-hedral geometry, formed by a monodentate carboxyl-ate group and three phenyl rings. The conformation is stabilized by an intra-molecular C-H?O hydrogen bond, which generates an S(5) ring. The aromatic ring of the 4-chloro-3-nitro-benzoate ligand makes dihedral angles of 75.64?(12), 64.37?(12) and 2.97?(12)° with the three phenyl ligands. The O atoms of the nitro group are disordered over two sets of sites in a 0.817?(5):0.183?(5) ratio. In the crystal, mol-ecules are linked via inter-molecular C-H?O hydrogen bonds into chains running parallel to [010].

| S-EPMC3200665 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data