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Catena-Poly[[triphenyl-tin(IV)]-?-2-(cyclo-hexyl-amino-carbon-yl)benzoato-?O:O].


ABSTRACT: In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl-tin cations are bridged by the N-cyclo-hexyl-phthalamate anion through the carboxyl-ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl-ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal.

SUBMITTER: Imtiaz-Ud-Din 

PROVIDER: S-EPMC3007350 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[triphenyl-tin(IV)]-μ-2-(cyclo-hexyl-amino-carbon-yl)benzoato-κO:O].

Imtiaz-Ud-Din   Raqiqt-Ul-Rasool   Bhatti Moazzam H MH   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8


In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl-tin cations are bridged by the N-cyclo-hexyl-phthalamate anion through the carboxyl-ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl-ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal. ...[more]

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