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Catena-Poly[[triphenyl-tin(IV)]-?-phenyl-phosphinato-?O:O'].

ABSTRACT: In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H?? inter-actions, forming a two-dimensional network lying parallel to (001).

SUBMITTER: Diop T

PROVIDER: S-EPMC3238605 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[triphenyl-tin(IV)]-μ-phenyl-phosphinato-κO:O'].

Diop Tidiane T Diop Libasse L Kociok-Köhn Gabriele G Molloy Kieran C KC Stoeckli-Evans Helen H

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H⋯π inter-actions, forming a two-dimensional network lying parallel to (001). ...[more]

PMID: 22199496

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