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Catena-Poly[[triphenyl-tin(IV)]-?-phenyl-phosphinato-?O:O'].

ABSTRACT: In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H?? inter-actions, forming a two-dimensional network lying parallel to (001).

SUBMITTER: Diop T

PROVIDER: S-EPMC3238605 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[triphenyl-tin(IV)]-μ-phenyl-phosphinato-κO:O'].

Diop Tidiane T Diop Libasse L Kociok-Köhn Gabriele G Molloy Kieran C KC Stoeckli-Evans Helen H

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H⋯π inter-actions, forming a two-dimensional network lying parallel to (001). ...[more]

PMID: 22199496

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catena-Poly[[triphenyl-tin(IV)]-?-3-methyl-phenyl-seleninato-?O:O'].

Project description:In the polymeric title coordination compound, [Sn(C(6)H(5))(3)(C(7)H(7)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intra-chain C-H?O hydrogen bond is observed.

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catena-Poly[[trimethyl-tin(IV)]-?-2-phenyl-butano-ato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(10)H(11)O(2))](n), the Sn atom has a distorted trigonal-bipyramidal coordination geometry, with two O atoms of two symmetry-related carboxyl-ate ligands in axial positions and three methyl groups in equatorial positions. In the crystal structure, carboxyl-ate bridges link the metal atoms, forming zigzag chains parallel to the b axis.

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catena-Poly[[trimethyl-tin(IV)]-?-phenyl-seleninato-?O:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

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catena-Poly[[trimethyl-tin(IV)]-?-2-(2-chloro-phenyl)-acetato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(8)H(6)ClO(2))](n), the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl-ate O atoms of the 2-chloro-phenyl-acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chloro-phenyl-acetato ligand, forming a chain structure.

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catena-Poly[[triphenyl-tin(IV)]-?-2-(cyclo-hexyl-amino-carbon-yl)benzoato-?O:O].

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catena-Poly[[tri-phenyl-tin(IV)]-?-N-(4-acetyl-phen-yl)maleamato].

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catena-Poly[[triphenyl-tin(IV)]-?-2-(2-picolinoylhydrazono)propanoato-?O:O].

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(Benzyl phenyl sulfoxide-?O)-chlorido-triphenyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(3)Cl(C(13)H(12)OS)], is situated within a distorted C(3)ClO trigonal-bipyramidal coordination geometry with a mean Sn-C distance of 2.136?(6)?Å and with an Sn-O distance of 2.393?(4)?Å. The Sn(IV) atom lies 0.171?(3)?Å out of the equatorial C(3) plane in the direction of the axially bound Cl atom.

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catena-Poly[[tribenzyl-tin(IV)]-?-(E)-3-phenyl-prop-2-enoato-?O:O'].

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