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Diacetato-(N,N-diethyl-ethylenediamine)-zinc(II).

ABSTRACT: In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl-ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra-hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with two different C-O distances of 1.234?(4) and 1.275?(4)?Å. The dihedral angle between the N/Zn/N and O/Zn/O planes is 83.11?(8)°. There are two independent mol-ecules in the asymmetric unit. N-H?O hydrogen bonding links mol-ecules into a three-dimensional network.

SUBMITTER: Kim YI

PROVIDER: S-EPMC3007483 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Diacetato-(N,N-diethyl-ethylenediamine)-zinc(II).

Kim Young-Inn YI Yun Sun-Young SY Lee Taewoo T Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl-ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra-hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with two different C-O distances of 1.234 (4) and 1.275 (4) Å. The dihedral angle between the N/Zn/N and O/Zn/O planes is 83.11 (8)°. There are two independent mol-ecules in the asymmetric unit. N-H⋯O hydrog ...[more]

PMID: 21588172

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