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Aqua-(imino-diacetato-κO,N,O')(1,10-phenanthroline-κN,N')zinc(II) sesquihydrate.

ABSTRACT: The imino-diacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through O-H⋯O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water mol-ecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component.

SUBMITTER: Ng HL 

PROVIDER: S-EPMC2967921 | biostudies-literature |

REPOSITORIES: biostudies-literature

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