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Diacetonitrile-(3-{2-[8-(2-bromo-eth-oxy)-9,10-dioxoanthracen-1-yl-oxy]eth-yl}-1-(2-pyridyl-meth-yl)imidazolium)silver(I) bis-(hexa-fluorido-phosphate).


ABSTRACT: The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol-ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexa-fluorido-phosphate anions, one of which is disordered over two positions in a 0.756?(11):0.244?(11) ratio. Weak ?-? inter-actions between the anthraquinone ring systems [centroid-centroid distance = 3.676?(3)?Å], inter-molecular Ag-? inter-actions [Cg?Ag = 3.405?Å] and C-H?? inter-actions between pairs of adjacent mol-ecules are observed.

SUBMITTER: Wen QS 

PROVIDER: S-EPMC3007485 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Diacetonitrile-(3-{2-[8-(2-bromo-eth-oxy)-9,10-dioxoanthracen-1-yl-oxy]eth-yl}-1-(2-pyridyl-meth-yl)imidazolium)silver(I) bis-(hexa-fluorido-phosphate).

Wen Qing-Song QS   Zhou Cheng-Lin CL   Qin Da-Bin DB  

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8


The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol-ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexa-fluorido-phosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π-π inter-actions between the anthraquinone ring systems [centroid-centroi  ...[more]

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