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(?-Cyclo-penta-dien-yl)[?-diethyl eth-yl(phen-yl)malonate]iron(II) hexa-fluorido-phosphate.

ABSTRACT: At 223?(2)?K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10?(14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (-) anion were found to be equally disordered over two sites.

SUBMITTER: Jenkins HA 

PROVIDER: S-EPMC2959750 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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(η-Cyclo-penta-dien-yl)[η-diethyl eth-yl(phen-yl)malonate]iron(II) hexa-fluorido-phosphate.

Jenkins Hilary A HA   Masuda Jason D JD   Piórko Adam A  

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (-) anion were found to be equally disordered over two sites. ...[more]

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