Ontology highlight
ABSTRACT:
SUBMITTER: Shin JW
PROVIDER: S-EPMC3007561 | biostudies-literature | 2010 Jul
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100710 Pt 8
In the title thio-cyanate-coordinated aza-macrocyclic copper(II) complex, [Cu(NCS)(2)(C(24)H(38)N(6))], the Cu(II) atom is coordinated by the four secondary N atoms of the aza-macrocyclic ligand and by the two N atoms of the thio-cyanate ions in a tetra-gonally distorted octa-hedral geometry. The average equatorial Cu-N bond length is shorter than the average axial Cu-N bond length [2.010 (2) and 2.528 (4) Å, respectively]. An N-H⋯N hydrogen-bonding inter-action between the secondary amine N ato ...[more]