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2-[(E)-(2-Chloro-phen-yl)imino-meth-yl]-6-methyl-phenol.

ABSTRACT: The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl-salicyl-aldehyde, crystallizes in the phenol-imine tautomeric form with an E conformation for the imine functionality. The mol-ecule is not planar, the dihedral angle between the aromatic rings being 36.38?(5)°. The hy-droxy H atom is involved in a strong intra-molecular O-H?N hydrogen bond, generating an S(6) ring.

SUBMITTER: Zhu P

PROVIDER: S-EPMC3008053 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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2-[(E)-(2-Chloro-phen-yl)imino-meth-yl]-6-methyl-phenol.

Zhu Peihua P Yu Jiemei J Wang Hongyan H Zhang Chunlai C Yang Dongming D

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl-salicyl-aldehyde, crystallizes in the phenol-imine tautomeric form with an E conformation for the imine functionality. The mol-ecule is not planar, the dihedral angle between the aromatic rings being 36.38 (5)°. The hy-droxy H atom is involved in a strong intra-molecular O-H⋯N hydrogen bond, generating an S(6) ring. ...[more]

PMID: 21588779

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