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4-[(3-Chloro-2-methyl-phen-yl)imino-meth-yl]phenol.

ABSTRACT: In the title compound, C(14)H(12)ClNO, the dihedral angle between the aromatic rings is 39.84?(7)°. In th crystal, mol-ecules are connected by O-H?N hydrogen bonds into chains parallel to [001]. In addition, a C-H?? contact occurs.

SUBMITTER: Manjunath BC

PROVIDER: S-EPMC3515282 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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4-[(3-Chloro-2-methyl-phen-yl)imino-meth-yl]phenol.

Manjunath B C BC Abdoh M M M MM Mallesha L L Mohana K N KN Lokanath N K NK

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

In the title compound, C(14)H(12)ClNO, the dihedral angle between the aromatic rings is 39.84 (7)°. In th crystal, mol-ecules are connected by O-H⋯N hydrogen bonds into chains parallel to [001]. In addition, a C-H⋯π contact occurs. ...[more]

PMID: 23284502

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4-Chloro-2-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(13)H(9)Cl(2)NO, was crystallized from a methanol solution of 5-chloro-salicylaldehyde and o-chloro-aniline. The mol-ecule displays a trans configuration with respect to the imine C=N double bond. The N atom is involved in an intra-molecular O-H?N hydrogen bond. The two aromatic rings are essentially coplanar, the dihedral angle between them being 7.1?(1)°. A C-H?? inter-action is present in the crystal.

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Project description:In the title compound, C(14)H(13)NO, the two rings show significant deviation from coplanarity, with a dihedral angle between the two planes of 49.40 (5)°. The hy-droxy group is involved in an inter-molecular O-H⋯N hydrogen bond, forming an extended one-dimensional zigzag chain along (001).

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Project description:The asymmetric unit of the title compound, C(19)H(22)ClNO, contains two independent mol-ecules in which the dihedral angles between the aromatic rings are 76.45?(9) and 74.69?(9)°. An intra-molecular O-H?N hydrogen bond occurs in each mol-ecule. The crystal structure features weak C-H?? inter-actions.

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4-Bromo-2-[(E)-(4-chloro-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(13)H(9)BrClNO, the dihedral angle between the substituted benzene rings is 43.90?(11)°. Strong intra-molecular O-H?N hydrogen bonds generate S(6) ring motifs. The crystal structure features short intemolecular Br?Br [3.554?(2)?Å] and Cl?Cl [3.412?(2)?Å] contacts. The crystal packing is further stabilized by inter-molecular C-H?O and C-H?? inter-actions.

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2-[(2-Bromo-phen-yl)imino-meth-yl]-6-methyl-phenol.

Project description:In the title compound, C(14)H(12)BrNO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the two aromatic rings is 34.26?(9)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring.

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