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4-Chloro-2-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.

ABSTRACT: The title compound, C(13)H(9)Cl(2)NO, was crystallized from a methanol solution of 5-chloro-salicylaldehyde and o-chloro-aniline. The mol-ecule displays a trans configuration with respect to the imine C=N double bond. The N atom is involved in an intra-molecular O-H?N hydrogen bond. The two aromatic rings are essentially coplanar, the dihedral angle between them being 7.1?(1)°. A C-H?? inter-action is present in the crystal.

SUBMITTER: Zhang X

PROVIDER: S-EPMC2968492 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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4-Chloro-2-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.

Zhang Xinli X

Acta crystallographica. Section E, Structure reports online 20090211 Pt 3

The title compound, C(13)H(9)Cl(2)NO, was crystallized from a methanol solution of 5-chloro-salicylaldehyde and o-chloro-aniline. The mol-ecule displays a trans configuration with respect to the imine C=N double bond. The N atom is involved in an intra-molecular O-H⋯N hydrogen bond. The two aromatic rings are essentially coplanar, the dihedral angle between them being 7.1 (1)°. A C-H⋯π inter-action is present in the crystal. ...[more]

PMID: 21582175

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