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2-[(E)-(2,3-Dimethyl-phen-yl)imino-meth-yl]phenol.

ABSTRACT: In the title compound, C(15)H(15)NO, the almost planar 2,3-dimethyl-aniline unit and the salicyl-aldehyde group (r.m.s. deviations of 0.0156 and 0.0109?Å, respectively) are oriented at a dihedral angle of 43.69?(9)° with respect to each other. An S(6) ring motif is formed due to intra-molecular O-H?N hydrogen bonding. In the crystal, C-H?? inter-actions occur between the 2,3-dimethyl-aniline unit and the salicyl-aldehyde group, where the CH is from the o-methyl group.

SUBMITTER: Tahir MN

PROVIDER: S-EPMC3008100 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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2-[(E)-(2,3-Dimethyl-phen-yl)imino-meth-yl]phenol.

Tahir M Nawaz MN Tariq Muhammad Ilyas MI Ahmad Shahbaz S Sarfraz Muhammad M Tariq Riaz H RH

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

In the title compound, C(15)H(15)NO, the almost planar 2,3-dimethyl-aniline unit and the salicyl-aldehyde group (r.m.s. deviations of 0.0156 and 0.0109 Å, respectively) are oriented at a dihedral angle of 43.69 (9)° with respect to each other. An S(6) ring motif is formed due to intra-molecular O-H⋯N hydrogen bonding. In the crystal, C-H⋯π inter-actions occur between the 2,3-dimethyl-aniline unit and the salicyl-aldehyde group, where the CH is from the o-methyl group. ...[more]

PMID: 21588761

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