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2-[(E)-(2,4-Dimethyl-phen-yl)imino-meth-yl]phenol.

ABSTRACT: The asymmetric unit of the title compound, C(15)H(15)NO, contains two independent mol-ecules, both of which exist in trans configurations with respect to the C=N bonds [1.278?(2) and 1.279?(2)?Å]. In each mol-ecule, intra-molecular O-H?N hydrogen bonds generate S(6) ring motifs. In one mol-ecule, the benzene rings form a dihedral angle of 13.38?(9)°, while in the other mol-ecule the dihedral angle is 30.60?(10)°. In the crystal, the two independent mol-ecules are linked via weak inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3212320 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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2-[(E)-(2,4-Dimethyl-phen-yl)imino-meth-yl]phenol.

Fun Hoong-Kun HK   Quah Ching Kheng CK   Viveka S S   Madhukumar D J DJ   Nagaraja G K GK  

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

The asymmetric unit of the title compound, C(15)H(15)NO, contains two independent mol-ecules, both of which exist in trans configurations with respect to the C=N bonds [1.278 (2) and 1.279 (2) Å]. In each mol-ecule, intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. In one mol-ecule, the benzene rings form a dihedral angle of 13.38 (9)°, while in the other mol-ecule the dihedral angle is 30.60 (10)°. In the crystal, the two independent mol-ecules are linked via weak inter-molecular  ...[more]

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