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μ-1,2-Di-4-pyridylethane-κN:N'-bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

ABSTRACT: In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C-H⋯S hydrogen bonds.

SUBMITTER: Avila V

PROVIDER: S-EPMC2961305 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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μ-1,2-Di-4-pyridylethane-κN:N'-bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

Avila Vanessa V Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20080418 Pt 5

In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C-H⋯S hydrogen bonds. ...[more]

PMID: 21202218

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