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N,N-Bis(diphenyl-phosphanyl)cyclo-propyl-amine.

ABSTRACT: In the title compound, C(27)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74?(5) and 68.23?(4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098?(2)?Å.

SUBMITTER: Engelbrecht I

PROVIDER: S-EPMC3009108 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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N,N-Bis(diphenyl-phosphanyl)cyclo-propyl-amine.

Engelbrecht Ilana I Visser Hendrik G HG Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

In the title compound, C(27)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74 (5) and 68.23 (4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098 (2) Å. ...[more]

PMID: 21589062

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