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{1,3-Bis[(diphenyl-phosphanyl-?P)-oxy]propane}dicarbonyl-iron(0).

ABSTRACT: The structure of the title compound, [Fe(C(27)H(26)O(2)P(2))(CO)(2)], exhibits a distorted tetra-hedral coordination [bond angle range = 96.31?(12)-119.37?(4)°], comprising two P-atom donors from the chelating 1,3-bis-[(diphenyl-phosphan-yl)-oxy]propane ligand [Fe-P = 2.1414?(10) and 2.1462?(10)?Å] and two carbonyl ligands [Fe-C = 1.763?(4) and 1.765?(3)?Å].

SUBMITTER: Xu G

PROVIDER: S-EPMC2979061 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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{1,3-Bis[(diphenyl-phosphanyl-κP)-oxy]propane}dicarbonyl-iron(0).

Xu Guoqiang G Li Xiaoyan X

Acta crystallographica. Section E, Structure reports online 20100421 Pt 5

The structure of the title compound, [Fe(C(27)H(26)O(2)P(2))(CO)(2)], exhibits a distorted tetra-hedral coordination [bond angle range = 96.31 (12)-119.37 (4)°], comprising two P-atom donors from the chelating 1,3-bis-[(diphenyl-phosphan-yl)-oxy]propane ligand [Fe-P = 2.1414 (10) and 2.1462 (10) Å] and two carbonyl ligands [Fe-C = 1.763 (4) and 1.765 (3) Å]. ...[more]

PMID: 21579032

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