Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{1,3-Bis[(diphenyl-phosphanyl-?P)-oxy]propane}dicarbonyl-iron(0).

ABSTRACT: The structure of the title compound, [Fe(C(27)H(26)O(2)P(2))(CO)(2)], exhibits a distorted tetra-hedral coordination [bond angle range = 96.31?(12)-119.37?(4)°], comprising two P-atom donors from the chelating 1,3-bis-[(diphenyl-phosphan-yl)-oxy]propane ligand [Fe-P = 2.1414?(10) and 2.1462?(10)?Å] and two carbonyl ligands [Fe-C = 1.763?(4) and 1.765?(3)?Å].

SUBMITTER: Xu G

PROVIDER: S-EPMC2979061 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

{1,3-Bis[(diphenyl-phosphanyl-κP)-oxy]propane}dicarbonyl-iron(0).

Xu Guoqiang G Li Xiaoyan X

Acta crystallographica. Section E, Structure reports online 20100421 Pt 5

The structure of the title compound, [Fe(C(27)H(26)O(2)P(2))(CO)(2)], exhibits a distorted tetra-hedral coordination [bond angle range = 96.31 (12)-119.37 (4)°], comprising two P-atom donors from the chelating 1,3-bis-[(diphenyl-phosphan-yl)-oxy]propane ligand [Fe-P = 2.1414 (10) and 2.1462 (10) Å] and two carbonyl ligands [Fe-C = 1.763 (4) and 1.765 (3) Å]. ...[more]

PMID: 21579032

Similar Datasets

{1,3-Bis[(diphenyl-phosphanyl-?P)-oxy]prop-2-yl-?C}iodido(trimethyl-phosphane)cobalt(II).

Project description:The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo-butane to a solution of the parent cobalt complex {1,3-bis-[(diphenyl-phosphan-yl)-oxy]prop-2-yl}bis-(trimethyl-phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of inter-nal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh(2) groups and a metallated Csp(3) atom. The Co(II) atom is centered in a trigonal-bipyramidal configuration.

| S-EPMC2979230 | biostudies-literature

1,3-Bis[(4-methylbenzylidene)amino-oxy]propane.

Project description:The title bis-oxime compound, C(19)H(22)N(2)O(2), synthesized by the reaction of 4-methyl-2-hydroxy-benzaldehyde with 1,3-bis-(amino-oxy)propane in ethanol, adopts a V-shaped conformation. The dihedral angle between the rings is 84.59?(3)°. The mol-ecule is disposed about a crystallographic twofold rotation axis, with one C atom lying on the axis. In the crystal, mol-ecules are packed by C-H??(Ph) inter-actions, forming chains.

| S-EPMC2971336 | biostudies-literature

[μ-1,3-Bis(diphenyl-phosphino)propane-κP:P']bis-[bromidogold(I)].

Project description:The title compound, [Au(2)Br(2)(C(27)H(26)P(2))], features linearly coordinated Au(I) atoms within P,Br-donor sets. The central portion of the mol-ecule is practically planar as quanti-fied by the Br-Au⋯Au-Br torsion angle of -169.9 (2)°. The P-Au-Br chromophores are twisted with respect to each other [dihedral angle = 52.3 (6)°]. The benzene rings on each P atom lie on either side of this plane. The Au atoms are positioned at the periphery of the mol-ecule, which facilitates the formation of Au⋯Au inter-actions [3.2575 (11) Å] that result in the formation of supra-molecular chains along the b-axis direction. The Au⋯Au inter-actions are responsible for the deviations from the ideal linear geometry for each Au atom.

| S-EPMC2979952 | biostudies-literature

trans-Bis(1,3-diphenyl-propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate.

Project description:In the title compound, [V(C15H11O2)2O(CH3OH)]·2CH3OH, the V(IV) atom is coordinated by two 1,3-diphenyl-propane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octa-hedral geometry is significantly distorted, with the V(IV) atom lying 0.330?(3)?Å above the equatorial plane formed by the O atoms of the two ?-diketonate ligands. In the crystal, O-H?O hydrogen bonds between the coordinating methanol group in the complex and the two methanol solvent mol-ecules lead to the formation of polymeric chains along the c-axis direction. Weak C-H?O contacts are also observed.

| S-EPMC3588710 | biostudies-literature

1,3-Bis[(4-nitro-benzyl-idene)amino-oxy]propane.

Project description:The complete molecule of title compound, C(17)H(16)N(4)O(6), is generated by a crystallographic twofold axis. Within the mol-ecule, the two benzene units are approximately perpen-dicular, making a dihedral angle of 85.91 (4)°. In the crystal, mol-ecules are linked into a three-dimensional network by C-H⋯O hydrogen bonds and short O⋯O and N⋯O inter-actions, with distances of 2.998 (2) and 2.968 (3) Å, respectively.

| S-EPMC2969883 | biostudies-literature

Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III).

Project description:In the title compound, [Cu(C??H??P?)?][GaCl?], the Cu(I) atom in the complex cation is P,P'-chelated by two 1,3-bis-(diphenyl-phosphan-yl)propane ligands in a distorted tetra-hedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetra-hedral geometry. In the crystal, weak C-H?? inter-actions occur between adjacent complex cations.

| S-EPMC3393151 | biostudies-literature

[1,3-Bis(diphenyl-phosphino)pentane-?P,P']tetra-carbonyl-chromium(0).

Project description:In the title compound, [Cr(C(29)H(30)P(2))(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and one bidentate phosphine ligand, which is bounded as a chelate in a cis position. The average Cr-P and Cr-C bond lengths are 2.377 and 1.865?Å, respectively.

| S-EPMC2968563 | biostudies-literature

[μ(2)-Bis(diphenyl-phosphanyl)methane][μ(3)-bis-(diphenyl-phosphanyl)meth-yl]trichlorido-tetra-gold(I) tetra-hydro-furan disolvate.

Project description:The title tetra-nuclear complex, [Au(4)(C(25)H(21)P(2))Cl(3)(C(25)H(22)P(2))]·2C(4)H(8)O, features two non-equivalent Ph(2)PCPPh(2) fragments, one of which represents the 'complete' mol-ecule (with two H atoms at the central C atom); each of the two P atoms of this mol-ecule is coordinated by an Au atom [Au-P = 2.2256 (13) and 2.2710 (13) Å], and these two Au atoms form an Au-Au bond [3.2945 (3) Å], thus closing the five-membered Au(2)P(2)C ring. The first of these Au atoms has a terminal chlorido ligand [Au-Cl = 2.2806 (12) Å], whereas the second Au atom forms a covalent bond with the central C atom of the bis-(diphenyl-phosphino)methyl group [Au-C = 2.114 (5) Å]; the latter group in turn coordinates with its P atoms the gold atoms of the Cl-Au-Au-Cl group [Au-P = 2.2356 (13) and 2.2338 (13), Au-Au = 3.3177 (3), Au-Cl = 2.3091 (12) and 2.2950 (13) Å], thus closing the second Au(2)P(2)C ring. The two such rings have different chemical functions, but both exhibit envelope conformations. However, the first (with different substituents at the Au atoms) is non-symmetrical with one of the P atoms in the flap position of the envelope; the other one has a conformation with mirror symmetry, and the gold-substituted C atom is displaced by 0.740 (5) Å from the almost exactly planar (r.m.s. deviation = 0.0038 Å) Au(2)P(2) group.

| S-EPMC3051681 | biostudies-literature

N,N-Bis(diphenyl-phosphanyl)cyclo-propyl-amine.

Project description:In the title compound, C(27)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74?(5) and 68.23?(4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098?(2)?Å.

| S-EPMC3009108 | biostudies-literature

Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV).

Project description:In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra-hedral coordination geometry formed by four P atoms [Ag-P = 2.460 (1)-2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn-C = 2.115 (4)-2.128 (4) Å;(Σ C-Sn-C)= 360.0 (6)°].

| S-EPMC2961205 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data