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Bis[N,N-bis-(diphenyl-phosphan-yl)cyclo-hexyl-amine-?P,P']platinum(II) bis-(hexa-fluorido-phosphate) dichloro-methane disolvate.

ABSTRACT: In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P-Pt-P bite angle of 70.76?(3)°. The cyclo-hexyl ring and one of the phenyl rings display 0.630?(7):0.37?(7) and 0.60?(2):0.40?(2) positional disorder, respectively. The dichloro-methane solvent mol-ecule displays 0.526?(4):0.474?(4) positional disorder. C-H?F hydrogen bonds stabilize the crystal packing.

SUBMITTER: Engelbrecht I

PROVIDER: S-EPMC3007244 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bis[N,N-bis-(diphenyl-phosphan-yl)cyclo-hexyl-amine-κP,P']platinum(II) bis-(hexa-fluorido-phosphate) dichloro-methane disolvate.

Engelbrecht Ilana I Visser Hendrik G HG Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P-Pt-P bite angle of 70.76 (3)°. The cyclo-hexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloro-methane solvent mol-ecule displays 0.526 (4):0.474 (4) positional disorder. C-H⋯F hydrogen bonds stabilize the cr ...[more]

PMID: 21588214

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