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(4S)-(-)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine.

ABSTRACT: The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis-ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the mol-ecular packing is stabilized by non-classical C-H?O hydrogen bonds.

SUBMITTER: Gzella AK

PROVIDER: S-EPMC3009175 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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(4S)-(-)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine.

Gzella Andrzej K AK Chrzanowska Maria M Dreas Agnieszka A Meissner Zofia Z

Acta crystallographica. Section E, Structure reports online 20101020 Pt 11

The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis-ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the mol-ecular packing is stabilized by non-classical C-H⋯O hydrogen bonds. ...[more]

PMID: 21589035

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