Unknown

Dataset Information

0

4,5,6,7,8,9-Hexahydro-2H-cyclo-octa[c]pyrazol-1-ium-3-olate.


ABSTRACT: The title compound, C(9)H(14)N(2)O, exists in the zwitterionic form in the crystal. The cyclo-octane ring adopts a twisted boat-chair conformation. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into sheets lying parallel to bc. The structure is also stabilized by ?-? inter-actions, with a centroid-to-centroid distance of 3.5684?(8)?Å.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3009207 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

altmetric image

Publications

4,5,6,7,8,9-Hexahydro-2H-cyclo-octa[c]pyrazol-1-ium-3-olate.

Fun Hoong-Kun HK   Yeap Chin Sing CS   Ragavan R Venkat RV   Vijayakumar V V   Sarveswari S S  

Acta crystallographica. Section E, Structure reports online 20101031 Pt 11


The title compound, C(9)H(14)N(2)O, exists in the zwitterionic form in the crystal. The cyclo-octane ring adopts a twisted boat-chair conformation. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into sheets lying parallel to bc. The structure is also stabilized by π-π inter-actions, with a centroid-to-centroid distance of 3.5684 (8) Å. ...[more]

Similar Datasets

| S-EPMC3213569 | biostudies-literature
| S-EPMC3009194 | biostudies-literature
| S-EPMC3998555 | biostudies-literature
| S-EPMC2977179 | biostudies-literature
| S-EPMC3297919 | biostudies-literature
| S-EPMC4120567 | biostudies-literature
| S-EPMC3100016 | biostudies-literature
| S-EPMC3007075 | biostudies-literature
| S-EPMC3379467 | biostudies-literature
| S-EPMC4257288 | biostudies-literature