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Cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth-oxy)quinoline-?N,O,N'](triphenylphosphane-?P)ruthenium(II) methanol monosolvate.

ABSTRACT: In the structure of the title compound, [RuCl(2)(C(16)H(14)N(2)O)(C(18)H(15)P)]·CH(3)OH, he Ru(II) ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmeth-oxy)quinoline acting as an N,O,N'-tridentate ligand, two Cl atoms, and one P atom from a PPh(3) ligand. The two Cl atoms adopt a cis arrangement with the PPh(3) ligand trans to one Cl atom. The N,O,N'-tridentate ligand occupies a mer position in the coordination sphere.

SUBMITTER: Xu HJ

PROVIDER: S-EPMC3011727 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth-oxy)quinoline-κN,O,N'](triphenylphosphane-κP)ruthenium(II) methanol monosolvate.

Xu Hui-Jun HJ Li Yu Y Du Qing-Yang QY

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12

In the structure of the title compound, [RuCl(2)(C(16)H(14)N(2)O)(C(18)H(15)P)]·CH(3)OH, he Ru(II) ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmeth-oxy)quinoline acting as an N,O,N'-tridentate ligand, two Cl atoms, and one P atom from a PPh(3) ligand. The two Cl atoms adopt a cis arrangement with the PPh(3) ligand trans to one Cl atom. The N,O,N'-tridentate ligand occupies a mer position in the coordination sphere. ...[more]

PMID: 21589336

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