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Bis(4-amino-benzoic acid-?N)dichloridozinc(II).

ABSTRACT: Mol-ecules of the title compound [ZnCl(2)(C(7)H(7)NO(2))(2)], are located on a twofold rotation axis. Two 4-amino-benzoic acid moieties, and two chloride ligands are coordinated to a Zn atom in a tetra-hedral fashion, forming an isolated mol-ecule. Neighbouring mol-ecules are linked through hydrogen-bonded carboxyl groups, as well as N-H?Cl hydrogen-bonding inter-actions between amine groups and the chloride ligands of neighbouring mol-ecules, forming a three-dimensional network.

SUBMITTER: Rademeyer M

PROVIDER: S-EPMC3011729 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bis(4-amino-benzoic acid-κN)dichloridozinc(II).

Rademeyer Melanie M Overbeek Gerhard E GE Liles David C DC

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

Mol-ecules of the title compound [ZnCl(2)(C(7)H(7)NO(2))(2)], are located on a twofold rotation axis. Two 4-amino-benzoic acid moieties, and two chloride ligands are coordinated to a Zn atom in a tetra-hedral fashion, forming an isolated mol-ecule. Neighbouring mol-ecules are linked through hydrogen-bonded carboxyl groups, as well as N-H⋯Cl hydrogen-bonding inter-actions between amine groups and the chloride ligands of neighbouring mol-ecules, forming a three-dimensional network. ...[more]

PMID: 21589307

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