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N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones.


ABSTRACT: A tandem C-H olefination/annulation sequence directed by N-acylsulfonamides affords a variety of isoindolinones. This transformation is compatible with aliphatic alkenes as well as conjugated alkenes. Notably, molecular oxygen can be used as the sole, eco-friendly oxidant.

SUBMITTER: Zhu C 

PROVIDER: S-EPMC3045675 | biostudies-literature | 2011 Mar

REPOSITORIES: biostudies-literature

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N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones.

Zhu Chen C   Falck J R JR  

Organic letters 20110208 5


A tandem C-H olefination/annulation sequence directed by N-acylsulfonamides affords a variety of isoindolinones. This transformation is compatible with aliphatic alkenes as well as conjugated alkenes. Notably, molecular oxygen can be used as the sole, eco-friendly oxidant. ...[more]

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