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Cis-(Pyridin-2-ylcarbonimidodithio-ato-?S,S')bis-(triphenyl-phosphane-?P)palladium(II).

ABSTRACT: The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions. The crystal structure features weak ?-? [centroid-centroid distance =3.7327(15)?Å] and C-H?? inter-actions and contains an almost spherically shaped void of 50.4?Å(3) per unit cell.

SUBMITTER: Bon VV

PROVIDER: S-EPMC3050130 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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cis-(Pyridin-2-ylcarbonimidodithio-ato-κS,S')bis-(triphenyl-phosphane-κP)palladium(II).

Bon Vladimir V VV Orysyk Svitlana I SI Pekhnyo Vasily I VI

Acta crystallographica. Section E, Structure reports online 20101208 Pt 1

The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions. The crystal structure features weak π-π [centroid-centroid distance =3.7327( ...[more]

PMID: 21522566

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