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{3-[Bis(2-pyridyl-methyl-?N)amino-?N]propanol}bis-(nitrato-?O)copper(II).

ABSTRACT: In the title compound, [Cu(NO(3))(2)(C(15)H(19)N(3)O)], the Cu(II) ion is coordinated by the N atoms of the tetra-dentate 3-[bis-(2-pyridyl-meth-yl)amino]-propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An inter-molecular O-H?O hydrogen-bonding inter-action between the free hy-droxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes.

SUBMITTER: Rowthu SR

PROVIDER: S-EPMC3050172 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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{3-[Bis(2-pyridyl-methyl-κN)amino-κN]propanol}bis-(nitrato-κO)copper(II).

Rowthu Sankara Rao SR Shin Jong Won JW Seo Yu Rim YR Min Kil Sik KS

Acta crystallographica. Section E, Structure reports online 20101215 Pt 1

In the title compound, [Cu(NO(3))(2)(C(15)H(19)N(3)O)], the Cu(II) ion is coordinated by the N atoms of the tetra-dentate 3-[bis-(2-pyridyl-meth-yl)amino]-propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An inter-molecular O-H⋯O hydrogen-bonding inter-action between the free hy-droxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes. ...[more]

PMID: 21522601

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