Unknown

Dataset Information

0

Catena-Poly[[[bis-(nitrato-?O)copper(II)]-bis-[?-1,3-bis-(imidazol-1-yl)-5-methyl-benzene-?(2)N(3):N(3')]] dihydrate].

ABSTRACT: In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93?(11) and 46.08?(12)°. The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supra-molecular structure by O-H?O and C-H?O hydrogen bonds.

SUBMITTER: Liu GX 

PROVIDER: S-EPMC3379180 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[bis-(nitrato-κO)copper(II)]-bis-[μ-1,3-bis-(imidazol-1-yl)-5-methyl-benzene-κ(2)N(3):N(3')]] dihydrate].

Liu Guang-Xiang GX  

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms  ...[more]

Similar Datasets

Unknown catena-Poly[[bis-(nitrato-?O)copper(II)]-?-1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)-benzene-?N:N'].
| S-EPMC3152049 | biostudies-literature
Unknown catena-Poly[[bis-(nitrato-?O)copper(II)]-bis-[?-1,4-bis-(pyridin-3-ylmeth-oxy)benzene-?N:N']].
| S-EPMC3120522 | biostudies-literature
Unknown catena-Poly[[zinc(II)-bis-[?-1,3-bis-(imidazol-1-ylmeth-yl)benzene-?N:N]] dinitrate methanol solvate].
| S-EPMC2971030 | biostudies-literature
Unknown catena-Poly[[[diaqua-manganese(II)]-bis-[μ-1,3-bis-(1H-imidazol-1-ylmeth-yl)benzene-κN:N]] dinitrate].
| S-EPMC3246916 | biostudies-literature
Unknown Poly[bis[?-1,3-bis-(imidazol-1-ylmeth-yl)benzene-?N:N]bis-(nitrato-?O)cadmium].
| S-EPMC3151839 | biostudies-other
Unknown catena-Poly[bis-[dimeth-yl(pyridine-?N)indium(III)]-?4-benzene-1,3-diolato-bis-[di-methyl-indium(III)]-?4-benzene-1,3-diolato].
| S-EPMC3884271 | biostudies-literature
Unknown catena-Poly[[aqua-[1,4-bis-(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl-isophthalato].
| S-EPMC3200974 | biostudies-literature
Unknown catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(1H-imidazol-1-yl)benzene].
| S-EPMC3011715 | biostudies-literature
Unknown catena-Poly[[(nitrato-?O,O')silver(I)]-?-N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine].
| S-EPMC3007296 | biostudies-literature
Unknown catena-Poly[cadmium-?-[1,3-bis-(imidazol-1-yl)propane]-di-?-chlorido].
| S-EPMC3379108 | biostudies-literature