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Trans-Bis(1H-indole-3-carbaldehyde thio-semicarbazonato-?N,S)nickel(II).

ABSTRACT: The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The -CH=N-N=C(S)-NH(2) frament is planar. Adjacent mol-ecules are linked by hydrogen bonds between the indolyl -NH (donor) site and the double-bond =N- (acceptor) site of an adjacent mol-ecule, forming a layer motif.

SUBMITTER: Rizal MR

PROVIDER: S-EPMC2961409 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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trans-Bis(1H-indole-3-carbaldehyde thio-semicarbazonato-κN,S)nickel(II).

Rizal Mohd Razali MR Ali Hapipah M HM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080517 Pt 6

The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The -CH=N-N=C(S)-NH(2) frament is planar. Adjacent mol-ecules are linked by hydrogen bonds between the indolyl -NH (donor) site and the double-bond =N- (acceptor) site of an adjacent mol-ecule, forming a layer motif. ...[more]

PMID: 21202507

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