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Bis(2,3,5,6-tetra-2-pyridyl-pyrazine-?N,N,N)nickel(II) dithio-cyanate dihydrate.

ABSTRACT: In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligands (tppz). Two thio-cyanate anions act as counter-ions and two water mol-ecules act as solvation agents. O-H?N hydrogen bonds are observed in the crystral structure.

SUBMITTER: De la Pinta N 

PROVIDER: S-EPMC3050193 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Bis(2,3,5,6-tetra-2-pyridyl-pyrazine-κN,N,N)nickel(II) dithio-cyanate dihydrate.

De la Pinta Noelia N   Fidalgo M Luz ML   Ezpeleta José M JM   Cortés Roberto R   Madariaga Gotzon G  

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligands (tppz). Two thio-cyanate anions act as counter-ions and two water mol-ecules act as solvation agents. O-H⋯N hydrogen bonds are observed in the crystral structure. ...[more]

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