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Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-?N,N',O)copper(II).

ABSTRACT: In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H?Cl and C-H?O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777?(3):0.223?(3)].

SUBMITTER: Ikmal Hisham NA

PROVIDER: S-EPMC3050288 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II).

Ikmal Hisham Nurul Azimah NA Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)]. ...[more]

PMID: 21522575

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