Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-?N,N',O)copper(II).

ABSTRACT: In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H?Cl and C-H?O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777?(3):0.223?(3)].

SUBMITTER: Ikmal Hisham NA

PROVIDER: S-EPMC3050288 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II).

Ikmal Hisham Nurul Azimah NA Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)]. ...[more]

PMID: 21522575

Similar Datasets

Bromido(2-{1-[2-(morpholin-4-yl)ethyl-imino]-eth-yl}phenolato)copper(II).

Project description:In the title complex, [CuBr(C(14)H(19)N(2)O(2))], the Cu(II) atom is coordinated by one phenolate O, one imine N and one amine N atom of the tridentate Schiff base ligand and by one bromide ion, resulting in a distorted CuBrN(2)O square-planar geometry, with the N atoms in a cis arrangement. The morpholine ring adopts a chair conformation.

| S-EPMC3007273 | biostudies-literature

Chlorido{?-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-?-oxido-dicopper(II) trihydrate.

Project description:In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H?Cl hydrogen bonds while O-H?O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

| S-EPMC3379123 | biostudies-literature

Chlorido{4-chloro-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato-κN,N',O}copper(II).

Project description:The Cu(II) atom in the title compound, [Cu(C(13)H(16)ClN(2)O(2))Cl], exists in a distorted square-planar coordination environment as the deprotonated Schiff base chelates to the Cu(II) atom through three atom sites. In the crystal structure, adjacent mol-ecules are linked by a Cu⋯Cl [3.011 (1) Å] bridge, generating a linear chain running along the b axis of the ortho-rhom-bic unit cell.

| S-EPMC2977511 | biostudies-literature

Chlorido{2-[1-(2-pyridylmethyl-imino)eth-yl]pyrrolato-κN,N',N''}copper(II).

Project description:The potential tridentate Schiff base ligand 2-[1-(2-pyridyl-methyl-imino)eth-yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl-pyrrole with 2-amino-methyl-pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl-amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.

| S-EPMC2960930 | biostudies-literature

Bis{2-[1-(benzyl-imino)-eth-yl]phenolato}palladium(II).

Project description:In the title compound, [Pd(C(15)H(14)NO)(2)], the Pd atom lies on an inversion center and is coordinated by two ligand mol-ecules through the O and N atoms in a bidentate manner, forming a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings in the ligand is 76.53 (19)°. The mol-ecular packing is stablized by C-H⋯O and C-H⋯π inter-actions.

| S-EPMC3007840 | biostudies-literature

Chlorido[4-chloro-2-(pyridin-2-yl-methyl-imino-meth-yl)phenolato-?(3)N,N',O]copper(II).

Project description:In the title complex, [Cu(C(13)H(10)ClN(2)O)Cl], the Cu(II) ion is coordinated by one O atom and two N atoms of the tridentate Schiff base ligand and one chloride ion, forming a slightly distorted square-planar geometry. Weak Cu?Cl inter-actions [2.793?(5)?Å] result in the formation of a chain along the a axis.

| S-EPMC3344299 | biostudies-literature

Di-?(1,1)-azido-bis-[(2-{1-[2-(isopropyl-amino)ethyl-imino]eth-yl}phenolato)copper(II)].

Project description:In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu?Cu separation is 3.2365?(3)?Å. A pair of intra-molecular N-H?O hydrogen bonds helps to establish the mol-ecular conformation.

| S-EPMC2979365 | biostudies-literature

Di-μ-chlorido-bis-[(2-{(E)-[(2,3-dihy-droxy-prop-yl)imino]-meth-yl}phenolato)copper(II)] methanol monosolvate.

Project description:In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra-molecular O-H⋯O hydrogen bonds occur. In the crystal, O-H⋯O hydrogen bonds join the components into a chain extending along the a axis.

| S-EPMC3246963 | biostudies-literature

Bis[2-(1-imino-eth-yl)phenolato-?N,O]nickel(II).

Project description:There are one and a half independent mol-ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol-ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter-molecular N-H?O hydrogen bonds link three mol-ecules into centrosymmetric trimer. The crystal packing exhibits weak inter-molecular C-H?O hydrogen bonds and voids of 37?Å(3).

| S-EPMC3254291 | biostudies-literature

(2,2'-Bipyridine)(2-{1-[2-(dimethyl-amino)ethyl-imino]eth-yl}-4-methoxy-phenolato)copper(II) perchlorate.

Project description:The Cu atom of the title complex, [Cu(C(13)H(19)N(2)O(2))(C(10)H(8)N(2))]ClO(4), has a distorted square-pyramidal geometry with all three of the donor atoms from the N,N',O-tridentate Schiff base ligand in the equatorial positions and the bipyridine N atoms in an equatorial-axial binding mode. The Cu atom is 0.1801 (11) Å above the N(3)O mean basal plane.

| S-EPMC2977620 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data