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Catena-Poly[[bis-(dimethyl-ammonium) [cadmate(II)-bis-(?-1,1':4',1''-terphenyl-3,3''-dicarboxyl-ato)]] dimethyl-formamide disolvate].

ABSTRACT: In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two ?(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two ?(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10].

SUBMITTER: Park SW 

PROVIDER: S-EPMC3050304 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(dimethyl-ammonium) [cadmate(II)-bis-(μ-1,1':4',1''-terphenyl-3,3''-dicarboxyl-ato)]] dimethyl-formamide disolvate].

Park Sang-Wook SW   Gu Ja-Min JM   Kim Youngmee Y   Huh Seong S  

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10]. ...[more]

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