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2-[(E)-(4-Methyl-phen-yl)imino-meth-yl]-6-(morpholin-4-ylmeth-yl)phenol.

ABSTRACT: In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q(T), ? and ? of 0.5642?(18)?Å, 177.32?(17) and ? = 10?(4)°, respectively. The two benzene rings make a dihedral angle of 42.67?(8)° with each other. An intra-molecular O-H?N hydrogen bond helps to stabilize the mol-ecular conformation. Aromatic C-H?? inter-actions and ?-? stacking inter-actions [centroid-centroid distance = 3.6155?(15)?Å] between the benzene rings contribute to the stabilization of the crystal structure.

SUBMITTER: Akkurt M 

PROVIDER: S-EPMC3050317 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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2-[(E)-(4-Methyl-phen-yl)imino-meth-yl]-6-(morpholin-4-ylmeth-yl)phenol.

Akkurt Mehmet M   Türktekin Sevim S   Jarrahpour Aliasghar A   Sharghi Hashem H   Badrabady Seid Ali Torabi SA   Aberi Mahdi M   Büyükgüngör Orhan O  

Acta crystallographica. Section E, Structure reports online 20101218 Pt 1

In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q(T), θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular conformation. Aromatic C-H⋯π inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.6155 (15) Å] between the benzen  ...[more]

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