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Dibromidobis[1-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine-?N]palladium(II).

ABSTRACT: In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra-hydro-pyrimidine group of the N-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C-N-Pd-Br torsion angle of 81.8?(4)°; this is different from the angle of 43.47?(14)°, reported in a closely related structure, dichloridobis(1-methyl-1,4,5,6-tetra-hydro-pyrimidine)-palladium(II).

SUBMITTER: Mao P

PROVIDER: S-EPMC3050419 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Dibromidobis[1-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine-κN]palladium(II).

Mao Pu P Liu Xiujun X Yang Liangru L Yuan Jinwei J Song Maoping M

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra-hydro-pyrimidine group of the N-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C-N-Pd-Br torsion angle of 81.8 (4)°; this is different from the angle of 43.47 (14)°, reported in a closely related structure, dichloridobis(1-methyl-1,4,5,6-tetra-hydro-pyrimidine)-palladium(II). ...[more]

PMID: 21522581

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