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Trans-Dichloridobis[dicyclo-hex-yl(2,4,6-trimethyl-phen-yl)phosphane-κP]palladium(II).

ABSTRACT: The title compound, [PdCl(2)(C(21)H(33)P)(2)], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd(II) atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760 (13) Å, while the Pd-Cl bond lengths are 2.3172 (14) Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclo-hex-yl(phen-yl)phosphane-κP]palladium(II), [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)] [Burgoyne et al. (2012 ▶). Acta Cryst. E68, m404].

SUBMITTER: Buthelezi I

PROVIDER: S-EPMC3515096 | biostudies-literature |

REPOSITORIES: biostudies-literature

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trans-Dichloridobis[dicyclo-hex-yl(phen-yl)phosphane-?P]palladium(II).

Project description:The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3343?(5)?Å, as the Pd atom lies on an inversion centre, while the Pd-Cl bond lengths are 2.3017?(4)?Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 ?). Inorg. Chem.33, 4804-4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 ?). Dalton Trans. pp. 4393-4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 ?). Eur. J. Inorg. Chem. pp. 397-407] (C(6)H(11) is cyclo-hexyl and C(7)H(7) is o-tol-yl). One of the cyclo-hexyl rings is disordered with the phenyl ring in a 0.587?(9):413?(9) ratio. Five long-range C-H?Cl inter-actions were observed within the structure.

| S-EPMC3343813 | biostudies-other

trans-Dichloridobis[dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane-?P]platinum(II) acetone monosolvate.

Project description:The title compound, [PtCl(2)(C(21)H(33)P)(2)]·C(3)H(6)O, crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment, with a P-Pt-P angle of 172.41?(3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55?(2):0.45?(2) and 0.58?(2):0.42?(2). The solvent mol-ecule was also disordered over two orientations in a 1:1 ratio. The crystal studied was a non-merohedral twin with a twin component of 32.4%.

| S-EPMC3254293 | biostudies-literature

trans-Dichloridobis{dicyclo-hex-yl[4-(dimethyl-amino)-phen-yl]phosphane-?P}platinum(II) dichloro-methane disolvate.

Project description:In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the Pt(II) atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt-P and Pt-Cl bond lengths of 2.3258?(6) and 2.3106?(6)?Å, respectively, and the P-Pt-Cl angles of 89.64?(2) and 90.36?(2)°. The effective cone angle for the dicyclo-hex-yl[4-(dimethyl-amino)-phen-yl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloro-methane solvent mol-ecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155].

| S-EPMC3588798 | biostudies-other

trans-Dichloridobis[diphen-yl(thio-phen-2-yl)phosphane-?P]palladium(II).

Project description:The title compound, trans-[PdCl(2)(C(16)H(13)PS)(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3387?(11)?Å, as the Pd atom lies on an inversion point, while the Pd-Cl bond lengths are 2.2950?(12)?Å.

| S-EPMC3344332 | biostudies-literature

trans-Dichloridobis[diphen-yl(4-vinyl-phen-yl)phosphane-?P]palladium(II).

Project description:In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3366?(7) and 2.2966?(7)?Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696?(15):0.304?(15) ratio.

| S-EPMC3238597 | biostudies-literature

trans-Carbonyl-chloridobis[dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Project description:The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh-P = 2.3237 (6) and 2.3253 (6) Å, Rh-Cl = 2.3724 (6) Å, Rh-C = 1.802 (2) Å, P-Rh-P = 173.42 (2)° and Cl-Rh-C = 179.13 (7)°. Effective cone angles for the two P atoms are 165 and 161°, respectively. Both isopropyl groups and the acetone mol-ecule are disordered with occupancy values of 0.523 (5):0.477 (5), 0.554 (8):0.446 (8) and 0.735 (4):0.265 (4), respectively. The crystal packing is stabilized by weak C-H⋯O and C-H⋯Cl contacts.

| S-EPMC3200912 | biostudies-literature

Dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane selenide.

Project description:In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H?Se and C-H?Cg contacts are observed (Cg is the centroid of the benzene ring).

| S-EPMC3295440 | biostudies-literature

trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).

Project description:The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3550?(7) and 2.2906?(7)?Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two ?-stacked rings of 3.505?(3)?Å. Intra- and intermolecular C-H?Cl hydrogen bonds also occur.

| S-EPMC3009084 | biostudies-other

trans-Dichloridobis(triphenyl-phosphane-?P)palladium(II) benzene hemisolvate.

Project description:The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024?Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ?). Acta Cryst. C39, 1015-1017].

| S-EPMC3343891 | biostudies-other

(Acetyl-acetonato-?O,O')carbon-yl{dicyclo-hex-yl[4-(dimethyl-amino)-phen-yl]phosphane-?P}rhodium(I).

Project description:The title compound, [Rh(C(5)H(7)O(2))(C(20)H(32)NP)(CO)], features an acetyl-acetonate-chelated Rh(I) cation coordinated by one P [Rh-P = 2.2525?(7)?Å], one carbonyl C [Rh-C = 1.792?(3)?Å] and two O [Rh-O = 2.0582?(17) and 2.0912?(18)?Å] atoms in a slightly distorted square-planar geometry. Mol-ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh-acetyl-acetonate backbone.

| S-EPMC3238760 | biostudies-literature

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