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(N,N,N',N'-Tetra-methyl-ethylenediamine-?N)bis-(2,4,6-trimethyl-phenolato-?O)germanium(II).

ABSTRACT: In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal-pyramidal geometry by two O atoms belonging to two 2,4,6-trimethyl-phenolate ligands and one N atom of a tetra-methyl-ethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge-O bonds are covalent and the Ge-N bond is coordinated.

SUBMITTER: Brusylovets O

PROVIDER: S-EPMC3297249 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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(N,N,N',N'-Tetra-methyl-ethylenediamine-κN)bis-(2,4,6-trimethyl-phenolato-κO)germanium(II).

Brusylovets Oleksii O Yrushnikov Oleg O Naumova Dina D Klishin Nikolai N Rusanov Eduard E

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal-pyramidal geometry by two O atoms belonging to two 2,4,6-trimethyl-phenolate ligands and one N atom of a tetra-methyl-ethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge-O bonds are covalent and the Ge-N bond is coordinated. ...[more]

PMID: 22412439

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