Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(N,N,N',N'-Tetra-methyl-ethylenediamine-?N)bis-(2,4,6-trimethyl-phenolato-?O)germanium(II).

ABSTRACT: In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal-pyramidal geometry by two O atoms belonging to two 2,4,6-trimethyl-phenolate ligands and one N atom of a tetra-methyl-ethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge-O bonds are covalent and the Ge-N bond is coordinated.

SUBMITTER: Brusylovets O

PROVIDER: S-EPMC3297249 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(N,N,N',N'-Tetra-methyl-ethylenediamine-κN)bis-(2,4,6-trimethyl-phenolato-κO)germanium(II).

Brusylovets Oleksii O Yrushnikov Oleg O Naumova Dina D Klishin Nikolai N Rusanov Eduard E

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal-pyramidal geometry by two O atoms belonging to two 2,4,6-trimethyl-phenolate ligands and one N atom of a tetra-methyl-ethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge-O bonds are covalent and the Ge-N bond is coordinated. ...[more]

PMID: 22412439

Similar Datasets

Poly[tetra-aqua-bis(?(2)-2,4,6-trinitro-phenolato)barium(II)].

Project description:The asymmetric unit of the title compound, [Ba(C(6)H(2)N(3)O(7))(2)(H(2)O)(4)](n), consists of a barium ion coordinated by two nitrophenolate ligands and four water mol-ecules. Barium is deca-coordinated by O atoms. These units are linked together through bridging nitro groups to form a one-dimensional polymeric chain. The three-dimensional packing is facilitated through hydrogen-bonding inter-actions mediated through water mol-ecules. The coordination distances around Ba vary from 2.728?(4) to 3.138?(5)?Å. The crystal sample, on exposure to air at room temperature for many days, slowly loses the water and peels out as filaments.

| S-EPMC2960753 | biostudies-literature

Bis(2,4,6-trimethyl-phen-yl)zinc(II).

Project description:The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl-phen-yl), crystallizes with a quarter of a mol-ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn-C bond length of 1.951?(5)?Å. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions.

| S-EPMC2969329 | biostudies-literature

Bis{2-[(2,4,6-trimethyl-phen-yl)imino-methyl]pyrrol-1-ido}palladium(II).

Project description:The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6?(7)/83.64?(7), 74.3?(7) and 88.3?(7)° with respect to the corresponding PdN(4) plane.

| S-EPMC3569194 | biostudies-literature

Bis(2,4,6-trimethyl-pyridinium) tetra-bromidozincate.

Project description:In the title compound, (C(8)H(12)N)(2)[ZnBr(4)], the coordination geometry of the anion is approximately tetra-hedral. The Zn-Br bond lengths range from 2.3901?(19) to 2.449?(2)?Å and the Br-Zn-Br angles range from 107.09?(8) to 112.48?(8)°. In the crystal, each [ZnBr(4)](2-) anion is connected to four cations through two N-H?Br and two C-H?Br hydrogen bonds, forming two-dimensional ?(cation)(2)?anion?(cation(2))? sheets parallel to the bc plane. Within each sheet, the anions are arranged in stacks with no significant inter-anion Br?Br inter-actions [the shortest being > 4.3?Å], while the cations are in chains, with weak ?-? stacking inter-actions [centroid-centroid distance = 3.991?Å] between cations inter-acting with the same anion.

| S-EPMC3515090 | biostudies-other

Tris(ethylenediamine)cobalt(II) bis(tetra-hydroxypentaborate) dihydrate.

Project description:The novel pentaborate with a transition-metal complex as counter-cation and with water of crystallization, tris(ethylenediamine)cobalt(II) bis[4,4',6,6'-tetrahydroxy-2,2'-spirobi(cyclotriboroxane)(1-)] dihydrate, [Co(C(2)H(8)N(2))(3)][B(5)O(6)(OH)(4)](2)·2H(2)O, forms a three-dimensional supra-molecular framework through O-H?O hydrogen bonding among the [B(5)O(6)(OH)(4)](-) anions with large channels along the a axis in which the templating [Co(en)(3)](2+) cations (en = ethylenediamine) and water mol-ecules are located. The crystal packing is consolidated by additional O-H?O and N-H?O hydrogen bonds.

| S-EPMC2968773 | biostudies-literature

Bis(trimethyl-phenyl-ammonium) tetra-bromidocuprate(II).

Project description:The crystal structure of the title compound, (C(9)H(14)N)(2)[CuBr(4)], consists of two quarternary ammonium cations and a tetra-hedral cuprate anions. Weak C-H⋯Br hydrogen bonding is present between the cation and anion in the crystal structure.

| S-EPMC2979935 | biostudies-literature

Bis(benzyl-trimethyl-ammonium) tetra-bromidocuprate(II).

Project description:In the title mol-ecular salt, (C(10)H(16)N)(2)[CuBr(4)], the Cu(II) ion adopts a squashed tetra-hedral geometry with Br-Cu-Br angles varying between 99.29 (3) and 132.53 (3)°. In the crystal, the components are linked by C-H⋯Br inter-actions, thereby generating a three-dimensional network.

| S-EPMC3200753 | biostudies-literature

trans-Bis(4-methoxy-thio-phenolato-κS)bis-(trimethyl-phosphine-κP)nickel(II).

Project description:The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy-thio-phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio-phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.

| S-EPMC2960343 | biostudies-literature

1,3-Bis(2,4,6-trimethyl-phen-yl)-3H-imidazol-1-ium tetra-oxidorhenate(VII).

Project description:The title compound, (C(21)H(25)N(2))[ReO(4)], was formed as the unexpected product in an attempted synthesis of a rhenium(I)-N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C-H⋯O hydrogen bond.

| S-EPMC3238778 | biostudies-literature

Dicarbonyl-dichlorido(N,N,N',N'-tetra-methyl-ethylenediamine)-ruthenium(II).

Project description:In the title compound, [RuCl(2)(C(6)H(16)N(2))(CO)(2)], the geometry around the Ru(II) atom is a distorted RuC(2)N(2)Cl(2) octa-hedron, with pairs of C and Cl atoms trans to each other and the N atoms of the bidentate ligand in a cis conformation. The five-membered chelate ring is puckered on the C-C bond.

| S-EPMC3152070 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data