Unknown

Dataset Information

0

(2,2'-Bipyridine)(pyridine-2,6-dicarboxyl-ato)oxidovanadium(IV) ethanol monosolvate.

ABSTRACT: In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octa-hedral coordination environment formed by two pyridyl N atoms of 2,2'-bipyridine (bpy), the vanadyl O atom, and two carboxyl-ate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxyl-ate (pydc(2-)) ligand. The pyridyl N atom of the pydc(2-) anion and one pyridyl N atom of bpy occupy the axial positions. O-H?O hydrogen bonds involving the ethanol solvent mol-ecule as donor and a carboxyl-ate O atom as acceptor atoms, as well as C-H?O hydrogen bonds, together with ?-? stacking inter-actions between adjacent aromatic rings (average centroid-centroid distance = 3.577?Å), seem to be effective in the stabilization of the crystal packing, resulting in the formation of a three-dimensional structure.

SUBMITTER: Aghabozorg H 

PROVIDER: S-EPMC3051467 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(2,2'-Bipyridine)(pyridine-2,6-dicarboxyl-ato)oxidovanadium(IV) ethanol monosolvate.

Aghabozorg Hossein H   Tavakoli Elnaz E   Mirzaei Masoud M  

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octa-hedral coordination environment formed by two pyridyl N atoms of 2,2'-bipyridine (bpy), the vanadyl O atom, and two carboxyl-ate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxyl-ate (pydc(2-)) ligand. The pyridyl N atom of the pydc(2-) anion and one pyridyl N atom of bpy occupy the axial positions. O-H⋯O hydrogen bonds involving the ethanol solvent mol-ecule as d  ...[more]

Similar Datasets

Unknown cis-Chloridobis(4,4'-dimethyl-2,2'-bipyridine-?(2)N,N')oxidovanadium(IV) chloride ethanol monosolvate monohydrate.
| S-EPMC3470179 | biostudies-literature
Unknown [(Pyridine-2,6-dicarboxyl-ato)copper(II)]-?-(pyridine-2,6-dicarboxyl-ato)-[bis-(ethyl-enediamine)-copper(II)]-?-(pyridine-2,6-dicarboxyl-ato)-[(pyridine-2,6-dicarboxyl-ato)copper(II)] ethyl-enediamine monosolvate tetra-hydrate.
| S-EPMC3379149 | biostudies-other
Unknown ?-4,4'-Bipyridine-bis-[aqua-(4-hy-droxy-pyridine-2,6-dicarboxyl-ato)copper(II)].
| S-EPMC3297272 | biostudies-literature
Unknown Poly[di-?(2)-aqua-?(5)-(pyridine-2,6-dicarboxyl-ato)-?(3)-(pyridine-2,6-dicarboxyl-ato)-cobalt(II)disodium].
| S-EPMC3238695 | biostudies-literature
Unknown Hexaaqua-nickel(II) tetra-aqua-bis-(?-pyridine-2,6-dicarboxyl-ato)bis-(pyridine-2,6-dicarboxyl-ato)trinickelate(II) octa-hydrate.
| S-EPMC3007465 | biostudies-literature
Unknown Poly[[tetra-aqua-bis-(μ(3)-pyridine-2,6-dicarboxyl-ato)(μ(2)-pyridine-2,6-dicarboxyl-ato)dilanthanum(III)] dihydrate].
| S-EPMC3200968 | biostudies-literature
Unknown catena-Poly[4,4'-bipyridinium [[tetra-aqua-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cerate(III)]-μ-pyridine-2,6-dicarboxyl-ato-κO:O,N,O-[(pyridine-2,6-dicarboxyl-ato-κO,N,O)cerate(III)]-μ-pyridine-2,6-dicarboxyl-ato-κO,N,O:O] penta-hydrate].
| S-EPMC3051934 | biostudies-literature
Unknown Bis(?-biphenyl-2,2'-dicarboxyl-ato)bis-[(2,2'-bipyridine)copper(II)].
| S-EPMC2960666 | biostudies-literature
Unknown Diaqua-(2,2'-bipyridine-6,6'-dicarboxyl-ato)nickel(II).
| S-EPMC3120548 | biostudies-literature
Unknown Poly[piperazinediium [[aqua-bismuth-ate(III)]-di-?-pyridine-2,6-dicarboxyl-ato-bis-muthate(III)-di-?-pyridine-2,6-dicarboxyl-ato] monohydrate].
| S-EPMC2960170 | biostudies-literature