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Cis-Chloridobis(4,4'-dimethyl-2,2'-bipyridine-?(2)N,N')oxidovanadium(IV) chloride ethanol monosolvate monohydrate.

ABSTRACT: In the title compound, [VClO(C(12)H(12)N(2))(2)]Cl·C(2)H(5)OH·H(2)O, the V(IV) atom is six-coordinated in a distorted octa-hedral geometry by four N atoms from two 4,4'-dimethyl-2,2'-bipyridine ligands, one O atom and one Cl atom. In the crystal, O-H?Cl, C-H?O and C-H?Cl hydrogen bonds and ?-? contacts between the pyridine rings [centroid-centroid distances = 3.7236?(17) and 3.6026?(19)?Å] stabilize the structure. Intra-molecular C-H?O and C-H?Cl hydrogen bonds are also present.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3470179 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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cis-Chloridobis(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')oxidovanadium(IV) chloride ethanol monosolvate monohydrate.

Shirvan Sadif A SA Haydari Dezfuli Sara S Golabi Elyas E Gholamzadeh Mohammad Amin MA

Acta crystallographica. Section E, Structure reports online 20120929 Pt 10

In the title compound, [VClO(C(12)H(12)N(2))(2)]Cl·C(2)H(5)OH·H(2)O, the V(IV) atom is six-coordinated in a distorted octa-hedral geometry by four N atoms from two 4,4'-dimethyl-2,2'-bipyridine ligands, one O atom and one Cl atom. In the crystal, O-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distances = 3.7236 (17) and 3.6026 (19) Å] stabilize the structure. Intra-molecular C-H⋯O and C-H⋯Cl hydrogen bonds are also present. ...[more]

PMID: 23125623

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