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(1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet-oxy-2-phenyl-ethen-yl]-3-eth-oxy-2-phenyl-bicyclo-[3.1.0]hexan-1-yl acetate.

ABSTRACT: The mol-ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo-propane ring plane is roughly perpendicular to the styryl group plane, forming a dihedral angle of 74.78?(19)°. The dihedral angle between the two benzene rings is 77.24?(6)°.

SUBMITTER: Hu WX

PROVIDER: S-EPMC3051501 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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(1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet-oxy-2-phenyl-ethen-yl]-3-eth-oxy-2-phenyl-bicyclo-[3.1.0]hexan-1-yl acetate.

Hu Wen-Xiang WX Xu Gao G Wei Guo-Qiang GQ

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

The mol-ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo-propane ring plane is roughly perpendicular to the styryl group plane, forming a dihedral angle of 74.78 (19)°. The dihedral angle between the two benzene rings is 77.24 (6)°. ...[more]

PMID: 21523163

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