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{5,10,15,20-Tetra-kis[4-(oct-yloxy)phen-yl]porphyrinato}copper(II).

ABSTRACT: In the title compound, [Cu(C(76)H(92)N(4)O(4))], the central Cu(II) ion is situated on an inversion centre. The porphyrinate core exhibits a nearly planar conformation [maximum deviation = 0.027?(3)?Å], with Cu-N distances of 1.997?(2) and 2.001?(2)?Å. The benzene rings of the 4-octyloxyphenyl groups are rotated at angles of 84.02?(8) and 77.02?(6)° with respect to the mean plane of the porphyrin fragment. The two terminal C atoms in the octyl group are disordered over two positions of equal occupancy.

SUBMITTER: Yang DL

PROVIDER: S-EPMC3238604 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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{5,10,15,20-Tetra-kis[4-(oct-yloxy)phen-yl]porphyrinato}copper(II).

Yang De-Liang DL Zhao Hong-Bin HB Liao Jun-Xu JX Chen Liang L Wang Bang-Ying BY

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the title compound, [Cu(C(76)H(92)N(4)O(4))], the central Cu(II) ion is situated on an inversion centre. The porphyrinate core exhibits a nearly planar conformation [maximum deviation = 0.027 (3) Å], with Cu-N distances of 1.997 (2) and 2.001 (2) Å. The benzene rings of the 4-octyloxyphenyl groups are rotated at angles of 84.02 (8) and 77.02 (6)° with respect to the mean plane of the porphyrin fragment. The two terminal C atoms in the octyl group are disordered over two positions of equal occ ...[more]

PMID: 22199495

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