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3-Meth-oxy-2-[(E)-(4-meth-oxy-phen-yl)imino-meth-yl]phenol.

ABSTRACT: The title compound, C(15)H(15)NO(3), adopts the enol-imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08?(5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047?(2)?Å. Such a planar conformation might be related to the occurrence of an intra-molecular O-H?N hydrogen bond. In the crystal, inter-molecular C-H?O hydrogen bonds link the mol-ecules into sheets parallel to (010). These sheets are inter-connected by weak C-H?? inter-actions.

SUBMITTER: Ozdemir Tari G 

PROVIDER: S-EPMC3051687 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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3-Meth-oxy-2-[(E)-(4-meth-oxy-phen-yl)imino-meth-yl]phenol.

Ozdemir Tari Gonca G   Işık Samil S   Ozkan Ramazan R   Alaman Ağar Ayşen A  

Acta crystallographica. Section E, Structure reports online 20110112 Pt 2

The title compound, C(15)H(15)NO(3), adopts the enol-imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047 (2) Å. Such a planar conformation might be related to the occurrence of an intra-molecular O-H⋯N hydrogen bond. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into sheets  ...[more]

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