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2,7-Dimethyl-2,7-diazo-niapyrene bis-(hexa-fluoro-phosphate).

ABSTRACT: In the title compound, C(16)H(14)N(2) (2+)·2PF(6) (-), the 2,7-dimethyl-2,7-diaza-pyrenium (DM-diaz) cation lies on a crystallographic twofold rotation axes. The diaz groups are nearly coplanar, with a maximum deviation of 0.008?(3)?Å. In the crystal, mol-ecules are linked into a two-dimensional lamellar framework parallel to (104) through weak C-H?F inter-actions.

SUBMITTER: Ang L

PROVIDER: S-EPMC3051768 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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2,7-Dimethyl-2,7-diazo-niapyrene bis-(hexa-fluoro-phosphate).

Ang Li L

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

In the title compound, C(16)H(14)N(2) (2+)·2PF(6) (-), the 2,7-dimethyl-2,7-diaza-pyrenium (DM-diaz) cation lies on a crystallographic twofold rotation axes. The diaz groups are nearly coplanar, with a maximum deviation of 0.008 (3) Å. In the crystal, mol-ecules are linked into a two-dimensional lamellar framework parallel to (104) through weak C-H⋯F inter-actions. ...[more]

PMID: 21523159

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