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N-[Bis(dimethyl-amino)-methyl-idene]-2-[(triphenyl-meth-yl)sulfan-yl]ethanaminium hexa-fluoro-phosphate.

ABSTRACT: The mol-ecular structure of the title compound, C(26)H(32)N(3)S(+)·PF(6) (-), shows a protonated guanidyl group bridged by an ethyl-ene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N-C(gua) bonds. The N-C-C-S group shows a folded nonplanar conformation with a torsion angle of 158.4?(1)°. In the crystal, the cation and anion are linked by an N-H?F inter-action.

SUBMITTER: Neuba A

PROVIDER: S-EPMC3089070 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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N-[Bis(dimethyl-amino)-methyl-idene]-2-[(triphenyl-meth-yl)sulfan-yl]ethanaminium hexa-fluoro-phosphate.

Neuba Adam A Flörke Ulrich U Henkel Gerald G

Acta crystallographica. Section E, Structure reports online 20110429 Pt 5

The mol-ecular structure of the title compound, C(26)H(32)N(3)S(+)·PF(6) (-), shows a protonated guanidyl group bridged by an ethyl-ene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N-C(gua) bonds. The N-C-C-S group shows a folded nonplanar conformation with a torsion angle of 158.4 (1)°. In the crystal, the cation and anion are linked by an N-H⋯F inter-action. ...[more]

PMID: 21754533

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