Ontology highlight
ABSTRACT:
SUBMITTER: Assey G
PROVIDER: S-EPMC3393214 | biostudies-literature | 2012 Jul
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120623 Pt 7
In the title complex, [Co(C(18)H(18)N(2)O(4))(C(2)H(3)O(2))(H(2)O)]·2CH(3)OH, the Co(III) atom is hexa-coordinated by water and acetate groups in the axial positions and by the tetra-dentate Schiff base occupying equatorial positions. These axial bonds are longer than the equatorial bonds to the tetra-dentate Schiff base. Two mol-ecules form a dimer through strong hydrogen bonds from the coordinated water of one mol-ecule to the meth-oxy O atoms of an adjoining mol-ecule. There is extensive intr ...[more]