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Enantioselective rhodium-catalyzed [4+2] cycloaddition of ?,?-unsaturated imines and isocyanates.


ABSTRACT: A [4+2] cycloaddition of ?,?-unsaturated imines and isocyanates catalyzed by a phosphoramidite-rhodium complex provides pyrimidinones in good yields and high enantioselectivities.

SUBMITTER: Oberg KM 

PROVIDER: S-EPMC3069138 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates.

Oberg Kevin M KM   Rovis Tomislav T  

Journal of the American Chemical Society 20110314 13


A [4+2] cycloaddition of α,β-unsaturated imines and isocyanates catalyzed by a phosphoramidite-rhodium complex provides pyrimidinones in good yields and high enantioselectivities. ...[more]

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