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(2-Chloro-4-nitro-benzoato)(methanol)triphenyl-tin(IV).

ABSTRACT: In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal-bipyramidal environment, formed by a monodentate carboxyl-ate group, three phenyl rings and a methanol mol-ecule. The axial sites are occupied by the O atoms of the methanol mol-ecule and the carboxyl-ate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitro-benzoate ligand makes dihedral angles of 66.18?(7), 74.71?(7) and 77.39?(7)° with respect to the three phenyl rings. In the crystal, the mol-ecules are linked via inter-molecular O-H?O and C-H?O hydrogen bonds into a column along the b axis.

SUBMITTER: Win YF

PROVIDER: S-EPMC3089065 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(2-Chloro-4-nitro-benzoato)(methanol)triphenyl-tin(IV).

Win Yip-Foo YF Choong Chen-Shang CS Ha Sie-Tiong ST Quah Ching Kheng CK Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal-bipyramidal environment, formed by a monodentate carboxyl-ate group, three phenyl rings and a methanol mol-ecule. The axial sites are occupied by the O atoms of the methanol mol-ecule and the carboxyl-ate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitro-benzoate ligand makes dihedral angles of 66.18 (7), 7 ...[more]

PMID: 21754275

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