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2-{(E)-N-[2-(1H-Inden-3-yl)eth-yl]imino-meth-yl}-1H-imidazole.

ABSTRACT: The asymmetric unit of the title compound, C(15)H(15)N(3), contains two crystallographically independent mol-ecules with very similar geometries. The imidazole and indenyl planes are approximately orthogonal, making dihedral angles of 88.21?(9) and 83.08?(9)%deg; in the two independent molecules. In the crystal, the imidazole units are linked by N-H?N hydrogen bonds into chains parallel to the 101) plane stretched in the diagonal direction [translation vector ([Formula: see text],1,0); C(4) motif]. Within a chain, there are two types of symmetrically non-equivalent alternating H-bonds which slightly differ in their parameters.

SUBMITTER: Li Z

PROVIDER: S-EPMC3089109 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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2-{(E)-N-[2-(1H-Inden-3-yl)eth-yl]imino-meth-yl}-1H-imidazole.

Li Zhao Z Tian Chong C Nie Wanli W Borzov Maxim V MV

Acta crystallographica. Section E, Structure reports online 20110416 Pt 5

The asymmetric unit of the title compound, C(15)H(15)N(3), contains two crystallographically independent mol-ecules with very similar geometries. The imidazole and indenyl planes are approximately orthogonal, making dihedral angles of 88.21 (9) and 83.08 (9)%deg; in the two independent molecules. In the crystal, the imidazole units are linked by N-H⋯N hydrogen bonds into chains parallel to the 101) plane stretched in the diagonal direction [translation vector ([Formula: see text],1,0); C(4) moti ...[more]

PMID: 21754472

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