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[(E)-N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3,4,5-trimeth-oxy-benzohydrazidato-?N',O](pyridine-?N)copper(II).

ABSTRACT: In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl-aldehyde benzoyl-hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu-O and Cu-N bond lengths of 1.926 and 1.976?Å, respectively. The pyridine ring makes dihedral angles of 26.12?(13) and 11.08?(12)°, respectively, with the trimeth-oxy-phenyl and phenolate rings, which make a dihedral angle of 16.05?(12)° with one another.

SUBMITTER: Wang YM

PROVIDER: S-EPMC3089131 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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[(E)-N'-(5-Chloro-2-oxidobenzyl-idene-κO)-3,4,5-trimeth-oxy-benzohydrazidato-κN',O](pyridine-κN)copper(II).

Wang Yu-Min YM Lin Xiao-Hui XH Chen Zhen Z Jiang Hong-Li HL Zhang Chang-Jun CJ

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl-aldehyde benzoyl-hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu-O and Cu-N bond lengths of 1.926 and 1.976 Å, respectively. The pyridine ring makes dihedral angles of 26.12 (13) and 11.08 (12)°, respectively, with the trimeth-oxy-phenyl and phenolate rings, which mak ...[more]

PMID: 21754268

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Crystal structure of the mixed methanol and ethanol solvate of bis-{3,4,5-trimeth-oxy-<i>N</i>'-[1-(pyridin-2-yl)ethyl-idene]benzohydrazidato}zinc(II).

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