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Chloridobis[N'-(2-meth-oxy-benzyl-idene)-4-nitro-benzohydrazidato-?O,N'](4-methyl-pyridine-?N)cobalt(III).

ABSTRACT: In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl-pyridine ligand and one Cl atom, forming a distorted octa-hedral geometry. The Co(III) ion is displaced by 0.038?(2)?Å from the equatorial plane towards the axial Cl atom.

SUBMITTER: Wu QJ

PROVIDER: S-EPMC3052150 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Chloridobis[N'-(2-meth-oxy-benzyl-idene)-4-nitro-benzohydrazidato-κO,N'](4-methyl-pyridine-κN)cobalt(III).

Wu Qiong-Jie QJ Chen Xiao-Hua XH Jiang Jiang J Cai Bi-Qiong BQ Xie Yong-Ping YP

Acta crystallographica. Section E, Structure reports online 20110202 Pt 3

In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl-pyridine ligand and one Cl atom, forming a distorted octa-hedral geometry. The Co(III) ion is displaced by 0.038 (2) Å from the equatorial plane towards the axial Cl atom. ...[more]

PMID: 21522234

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