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(Acetyl-acetonato-?O,O')(2-bromo-4-chloro-6-{[2-(dimethyl-amino)-ethyl-imino]-meth-yl}phenolato-?N,N',O)oxidovanadium(IV).

ABSTRACT: The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl-acetonate anion, forming a distorted cis-VN(2)O(4) octa-hedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetyl-acetone ligand towards the oxide O atom is 0.256?(2)?Å.

SUBMITTER: Wang FM 

PROVIDER: S-EPMC3089186 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(Acetyl-acetonato-κO,O')(2-bromo-4-chloro-6-{[2-(dimethyl-amino)-ethyl-imino]-meth-yl}phenolato-κN,N',O)oxidovanadium(IV).

Wang Fu-Ming FM  

Acta crystallographica. Section E, Structure reports online 20110429 Pt 5

The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl-acetonate anion, forming a distorted cis-VN(2)O(4) octa-hedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetyl-acetone ligand towards the oxide O  ...[more]

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